3393-45-1

5,6-DIHYDRO-2H-PYRAN-2-ONE

5,6-DIHYDRO-2H-PYRAN-2-ONE

别名:
CasNo.: 3393-45-1
分子式: C5H6O2
分子量: 98.1014
储存条件:
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中文名称: 5,6-DIHYDRO-2H-PYRAN-2-ONE
英文名称: 5,6-DIHYDRO-2H-PYRAN-2-ONE
CasNo.: 3393-45-1
分子式: C5H6O2
分子量: 98.1014

Quality Factory Sells Top Purity 99% 5,6-DIHYDRO-2H-PYRAN-2-ONE 3393-45-1 with Safe Delivery

  • Molecular Formula:C5H6O2
  • Molecular Weight:98.1014
  • Vapor Pressure:0.055mmHg at 25°C 
  • Refractive Index:n20/D 1.483(lit.)  
  • Boiling Point:233.723 °C at 760 mmHg 
  • Flash Point:89.106 °C 
  • PSA:26.30000 
  • Density:1.12 g/cm3 
  • LogP:0.48950 

5,6-DIHYDRO-2H-PYRAN-2-ONE(Cas 3393-45-1) Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 1647, 1984 DOI: 10.1021/jo00183a030Tetrahedron Letters, 25, p. 4783, 1984 DOI: 10.1016/S0040-4039(01)81518-5

General Description

Enantioselective conjugate addition of Grignard reagents to 5,6-dihydro-2H-pyran-2-one catalyzed by a chiral phosphine-copper iodide catalyst has been reported.

InChI:InChI=1/C5H6O2/c6-5-3-1-2-4-7-5/h1,3H,2,4H2

3393-45-1 Relevant articles

Catalytic Allylic Oxidation of Cyclic Enamides and 3,4-Dihydro-2H-Pyrans by TBHP

Yu, Yang,Humeidi, Ranad,Alleyn, James R.,Doyle, Michael P.

, p. 8506 - 8513 (2017/08/23)

Allylic oxidation of heteroatom substitu...

Tandem cross enyne metathesis (CEYM)-intramolecular Diels-Alder reaction (IMDAR). An easy entry to linear bicyclic scaffolds

Miró, Javier,Sánchez-Roselló, María,Sanz, álvaro,Rabasa, Fernando,Del Pozo, Carlos,Fustero, Santos

supporting information, p. 1486 - 1493 (2016/04/09)

A new tandem cross enyne metathesis (CEY...

3393-45-1 Process route

(E)-N-benzyl-N-(but-3-en-1-yl)cinnamamide

(E)-N-benzyl-N-(but-3-en-1-yl)cinnamamide

phenylacetylene
536-74-3

phenylacetylene

5,6-dihydro-pyran-2-one
3393-45-1

5,6-dihydro-pyran-2-one

(8SR,8aSR)-2-benzyl-6,8-diphenyl-3,4,4a,7,8,8a-hexahydroisoquinolin-1(2H)-one

(8SR,8aSR)-2-benzyl-6,8-diphenyl-3,4,4a,7,8,8a-hexahydroisoquinolin-1(2H)-one

(8SR,8aRS)-2-benzyl-6,8-diphenyl-3,4,4a,7,8,8a-hexahydroisoquinolin-1(2H)-one

(8SR,8aRS)-2-benzyl-6,8-diphenyl-3,4,4a,7,8,8a-hexahydroisoquinolin-1(2H)-one

N-benzyl-N-[(Z)-5-phenylhexa-3,5-dien-1-yl]cinnamamide

N-benzyl-N-[(Z)-5-phenylhexa-3,5-dien-1-yl]cinnamamide

Conditions
Conditions Yield
With [1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(O-isopropoxyphenylmethylene)ruthenium; In toluene; at 90 ℃; for 48h; Overall yield = 78 %; diastereoselective reaction; Inert atmosphere; Sealed tube;
6 % de
3,4-dihydro-2<i>H</i>-pyran
110-87-2

3,4-dihydro-2H-pyran

5,6-dihydro-pyran-2-one
3393-45-1

5,6-dihydro-pyran-2-one

6-(3-phenylpropyl)-2H-pyran-4(3H)-one

6-(3-phenylpropyl)-2H-pyran-4(3H)-one

Conditions
Conditions Yield
Multi-step reaction with 2 steps
1.1: tert.-butyl lithium / tetrahydrofuran; pentane / 1 h / -78 - 0 °C / Inert atmosphere
1.2: 2 h / -78 °C / Inert atmosphere
2.1: tert.-butylhydroperoxide; sodium acetate; dirhodium tetrakis(caprolactamate); oxygen / water; dichloromethane / 20 °C
With tert.-butylhydroperoxide; dirhodium tetrakis(caprolactamate); tert.-butyl lithium; oxygen; sodium acetate; In tetrahydrofuran; dichloromethane; water; pentane;
 

3393-45-1 Upstream products

  • 536-74-3
    536-74-3

    phenylacetylene

  • 110-87-2
    110-87-2

    3,4-dihydro-2H-pyran

3393-45-1 Downstream products

  • 183504-77-0
    183504-77-0

    4-(4-chlorophenyl)tetrahydro-2H-pyran-2-one

  • 61198-49-0
    61198-49-0

    (S)-4-phenyltetrahydro-2H-pyran-2-one

  • 156496-88-7
    156496-88-7

    cis-3-(2,6-Dichlorophenyl)-3a,6,7,7a-tetrahydro-4H-pyrano[3,4-d]isoxazol-4-one

  • 61898-55-3
    61898-55-3

    (4R)-4-methyltetrahydro-2H-pyran-2-one

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