What is the 1,1'-DIBENZOYLFERROCENE?

1,1'-DIBENZOYLFERROCENE is , while it's Molecular Formula is C 24 H 18 FeO 2 . Used in Laboratory-Level Organic Chemistry: 1,1'-Dibenzoylferrocene is used as a key intermediate in the synthesis of various chemical compounds. Its stability and solubility properties contribute to its utility in this application, facilitating the creation of a wide range of organic compounds for research and development purposes. Used in Chemical Synthesis: 1,1'-Dibenzoylferrocene is employed as a starting material for the preparation of other organometallic compounds and derivatives. Its unique structure and reactivity make it a valuable component in the development of new chemical entities, potentially leading to advancements in various fields such as pharmaceuticals, materials science, and more. Used in Research and Development: In the realm of scientific research, 1,1'-dibenzoylferrocene serves as a versatile compound for exploring new reaction pathways and understanding the properties of organometallic compounds. Its use in this context can lead to the discovery of novel applications and the expansion of our knowledge in organic chemistry and related disciplines.

What is the CAS number for 1,1'-DIBENZOYLFERROCENE?

The CAS number of 1,1'-DIBENZOYLFERROCENE is 12180-80-2.

What is 1,1'-DIBENZOYLFERROCENE (12180-80-2) used for?

1,1'-Dibenzoylferrocene is an organometallic derivative of ferrocene, a chemical compound formed through the reaction of ferrocene with benzoyl chloride. It is known for its distinctive orange crystalline structure and remarkable stability in air. With a molecular formula of C24H20FeO2, this compound is reasonably soluble in polar organic solvents, making it a valuable intermediate in the synthesis of other chemical compounds, primarily in laboratory-level organic chemistry.

What is the 1,1'-DIBENZOYLFERROCENE?

1,1'-DIBENZOYLFERROCENE is , while it's Molecular Formula is C 24 H 18 FeO 2 . Used in Laboratory-Level Organic Chemistry: 1,1'-Dibenzoylferrocene is used as a key intermediate in the synthesis of various chemical compounds. Its stability and solubility properties contribute to its utility in this application, facilitating the creation of a wide range of organic compounds for research and development purposes. Used in Chemical Synthesis: 1,1'-Dibenzoylferrocene is employed as a starting material for the preparation of other organometallic compounds and derivatives. Its unique structure and reactivity make it a valuable component in the development of new chemical entities, potentially leading to advancements in various fields such as pharmaceuticals, materials science, and more. Used in Research and Development: In the realm of scientific research, 1,1'-dibenzoylferrocene serves as a versatile compound for exploring new reaction pathways and understanding the properties of organometallic compounds. Its use in this context can lead to the discovery of novel applications and the expansion of our knowledge in organic chemistry and related disciplines.

What is the CAS number for 1,1'-DIBENZOYLFERROCENE?

The CAS number of 1,1'-DIBENZOYLFERROCENE is 12180-80-2.

What is 1,1'-DIBENZOYLFERROCENE (12180-80-2) used for?

1,1'-Dibenzoylferrocene is an organometallic derivative of ferrocene, a chemical compound formed through the reaction of ferrocene with benzoyl chloride. It is known for its distinctive orange crystalline structure and remarkable stability in air. With a molecular formula of C24H20FeO2, this compound is reasonably soluble in polar organic solvents, making it a valuable intermediate in the synthesis of other chemical compounds, primarily in laboratory-level organic chemistry.

12180-80-2

1,1'-Dibenzoylferrocene

别名：

CasNo.： 12180-80-2

分子式： C24H18 Fe O2

分子量： 394.253

储存条件：

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中文名称： 1,1'-Dibenzoylferrocene

英文名称： 1,1'-Dibenzoylferrocene

CasNo.： 12180-80-2

分子式： C24H18 Fe O2

分子量： 394.253

Buy Good Quality 1,1'-Dibenzoylferrocene 12180-80-2 with a minimum purity of 99%

Molecular Formula:C₂₄H₁₈FeO₂
Molecular Weight:394.253
Melting Point:103 °C
Boiling Point:293.1 °C at 760 mmHg
Flash Point:124 °C
PSA：34.14000
Density:g/cm³
LogP:4.54670

12180-80-2 Relevant articles

1-Ethyl-3-methylimidazolium halogenoaluminate ionic liquids as solvents for Friedel-Crafts acylation reactions of ferrocene

Stark, Annegret,MacLean, Bonnie L.,Singer, Robert D.

, p. 63 - 66 (1999)

Friedel-Crafts acylations of ferrocene i...

Ruthenium-Catalyzed Enantioselective Hydrogenation of Ferrocenyl Ketones: A Synthetic Method for Chiral Ferrocenyl Alcohols

Lu, Bin,Wang, Qun,Zhao, Mengmeng,Xie, Xiaomin,Zhang, Zhaoguo

, p. 9563 - 9569 (2015/10/12)

Highly effective asymmetric hydrogenatio...

Acceptor-substituted ferrocenium salts as strong, single-electron oxidants: Synthesis, electrochemistry, theoretical investigations, and initial synthetic application

Khobragade, Dushant A.,Mahamulkar, Shraddha G.,Pospí?il, Lubomír,Císa?ová, Ivana,Rulí?ek, Lubomír,Jahn, Ullrich

supporting information, p. 12267 - 12277 (2012/11/14)

A series of mono- and 1,1'-diheteroatom-...

Asymmetric synthesis of planar chiral 2-mono- and 2,2′-disubstituted 1,1′-bisbenzoylferrocenes

Enders, Dieter,Klumpen, Thomas

, p. 698 - 709 (2007/10/03)

An efficient and flexible asymmetric syn...

Efficient regio- and diastereo-controlled synthesis of 1,1′- and 1,1′,2,2′-functionalised ferrocenes and the formation of 2-oxa[3]ferrocenophanes

Carroll, Michael A.,White, Andrew J.P.,Widdowson, David A.,Williams, David J.

, p. 1551 - 1557 (2008/10/08)

The synthesis of a C2 symmetric 1,1′ ,2,...

12180-80-2 Process route

: 102-54-5,55404-68-7
ferrocene

: 98-88-4
benzoyl chloride

: 12180-80-2,32983-90-7
1,1’-dibenzoylferrocene

Conditions

Conditions	Yield
With aluminium chloride; In dichloromethane; ferrocene (1.0 equiv.) added to a stirred suspension of benzoyl chloride(2.2 equiv.) and aluminium chloride (2.2 equiv.) in dichloromethane, st irred at room temp. overnight (16 h); washed with water, organic layer passed through a plug of alumina, washed with chloroform, washings concentrated in vacuo, crude product purified by flash column chromy. on silica gel (TLC Rf 0.26 (1:1 ether-hexane)), elem. anal.;	99%
With aluminium trichloride; In dichloromethane; to suspn. of AlCl3 in CH2Cl2 ligand was added, soln. of Fe-complex in CH2Cl2 was added, stirred for 3 ds at room temp. under Ar; aq. soln. of NaHCO3 was added, extd. with CH2Cl2, washed with aq. NaHCO3, dried over MgSO4, concd. under reduced pressure, column chromy. on silica gel with pentane-Et2O; elem. anal.;	87%
With aluminium trichloride; benzoyl chloride; In dichloromethane; soln. of C6H5COCl and AlCl3 in dry CH2Cl2 was added dropwise over a period of 1 h to a stirred soln. of ferrocene in dry CH2Cl2; soln. was refluxed for 30 min, hydrolized with 0.1 M HCl, product worked up; solid chromd. on alumina using benzene, following by ether ewluant;	86%
With aluminum (III) chloride; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere; Schlenk technique;	75%
With AlCl₃; In dichloromethane;

: 102-54-5,55404-68-7
ferrocene

: 98-88-4
benzoyl chloride

: 1272-44-2
benzoylferrocene

: 12180-80-2,32983-90-7
1,1’-dibenzoylferrocene

Conditions

Conditions	Yield
With 1-ethyl-3-methylimidazolium iodide-AlCl₃; (argon); very slow addn. of AlCl3 to 1-ethyl-3-methylimidazolium iodide, addn. of ferrocene to the ionic liquid, stirring (10 min), ice bath (0°C), addn. of BzCl, stirring (0°C, 2 h), quenching (2 M HCl); extraction (CH2Cl2), drying (MgSO4), concn. (vac.), column chromy. (SiO2, hexanes/ethyl acetate, 10:1 to 1:1);	83% 12%
With 1-ethyl-3-methylimidazolium iodide-AlCl₃; (argon); very slow addn. of AlCl3 to 1-ethyl-3-methylimidazolium iodide, addn. of ferrocene to the ionic liquid, stirring (10 min), ice bath (0°C), addn. of BzCl, stirring (0°C, 2 h), quenching (2 M HCl); extraction (CH2Cl2), drying (MgSO4), concn. (vac.), column chromy. (SiO2, hexanes/ethyl acetate, 10:1 to 1:1);	12% 83%
ferrocene; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In hexane; at 20 ℃; Inert atmosphere; benzoyl chloride; In tetrahydrofuran; dichloromethane; at -78 - 20 ℃; for 2.5h; Inert atmosphere;	65% 16%

12180-80-2 Upstream products

102-54-5
ferrocene
85-44-9
phthalic anhydride
98-88-4
benzoyl chloride

12180-80-2 Downstream products

251976-64-4
(C₅H₄COC₆H₅)Fe(CH₃OH)3⁽¹⁺⁾
12249-22-8
ferrocene-1,1' diylbis(diphenylmethanol)
267892-35-3
Fe(C₅H₄C(OH)(C₆H₅)CCC(CH₃)2OOC(CH₃)2CH₂CH₂CH₃)2
227937-09-9
1,1'-bis[(3-methylphenylimino)phenylmethyl]ferrocene

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