Acetylferrocene
Acetylferrocene
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- Molecular Formula:C12H12FeO
- Molecular Weight:228.074
- Appearance/Colour:orange crystalline powder
- Vapor Pressure:1.77mmHg at 25°C
- Melting Point:81-86 ºC
- Refractive Index:1.502
- Boiling Point:218 ºC at 760 mmHg
- Flash Point:99.1 ºC
- PSA：17.07000
- Density:1.014g/cm3
- LogP:1.99970
Acetylferrocene(Cas 1271-55-2) Usage
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Safety Profile |
Poison by ocular and intravenous routes. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes. |
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Purification Methods |
Orange-red crystals are obtained when it is recrystallised from isooctane or *C6H6, and then sublimed at 100o/1mm. The oxime has m 167-170o (from Et2O or aqueous EtOH). The semicarbazone has m 198-201o (from EtOH). [Richmond & Freiser J Am Chem Soc 77 2022 1955, Weinmayer J Am Chem Soc 77 3009 1955, Broadhead et al. J Chem Soc 650 1958, Beilstein 16 IV 1798.] |
InChI:InChI=1/C7H8O/c1-6(8)7-4-2-3-5-7/h2-5,7H,1H3
1271-55-2 Relevant articles
Metal complexation of thioacylferrocenes: crystal structures of pentacarbonyl(thiobenzoylferrocene-S)chromium and benzoylferrocene
Barnes, John C.,Bell, William,Glidewell, Christopher,Howie, R. Alan
, p. 369 - 378 (1990)
Acylferrocenes (C5H5)Fe(C5H4COR) (R=CH3,...
Improvement of ferrocene acylation. Conventional vs. microwave heating for scandium-catalyzed reaction in alkylmethylimidazolium-based ionic liquids
Berardi, Serena,Conte, Valeria,Fiorani, Giulia,Floris, Barbara,Galloni, Pierluca
, p. 3015 - 3020 (2008)
Acylation of ferrocene-catalyzed by scan...
Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts
Kizas, Ol'ga A.,Chaschin, Ivan S.,Godovikov, Ivan A.,Dolgushin, Fedor M.,Antonov, Dmitrii Yu.,Nikitin, Lev N.,Khokhlov, Alexei R.
, p. 368 - 370 (2017)
Cation CpFeC5H4–C+=CH2 was obtained by p...
The synthesis of ferrocenyl- and ferrocenoylpyrimidines
Zherebker,Rodionov,Pilipenko,Kachala,Nikitin,Belousova,Simenel
, (2014)
New derivatives of pyrimidine were synth...
Palladium-Catalyzed Removable 8-Aminoquinoline Assisted Chemo- and Regioselective Oxidative sp2-C-H/sp3-C-H Cross-Coupling of Ferrocene with Toluene Derivatives
Sattar, Moh.,Kumar, Sangit
, p. 5960 - 5963 (2017)
The coupling of the C(sp2)-H bond of fer...
Fabrication of bisferrocenyl derivative grafted HTPB with high iron content and its application in dopamine detection
Aghaiepour, Alireza,Rahimpour, Shabnam,Payami, Elmira,Mohammadi, Reza,Teimuri-Mofrad, Reza
, (2021)
In this work, we employed an efficient s...
Very high rate enhancement of benzyl alcohol oxidation by an artificial enzyme
Marinescu, Lavinia G.,Bols, Mikael
, p. 4590 - 4593 (2006)
(Figure Presented) Promoting the atomic ...
Tuneable superbase-catalyzed vinylation of α-hydroxyalkylferrocenes with alkynes
Trofimov, Boris A.,Oparina, Ludmila A.,Tarasova, Olga A.,Artem'ev, Alexander V.,Kobychev, Vladimir B.,Gatilov, Yuriy V.,Albanov, Alexander I.,Gusarova, Nina K.
, p. 5954 - 5960 (2014)
Superbase-catalyzed (KOH/DMSO suspension...
Synthesis, characterization and electrochemical properties of novel trinuclear ferrocenyl based organosilane compounds
Teimuri-Mofrad, Reza,Safa, Kazem D.,Rahimpour, Keshvar
, p. 36 - 44 (2014)
Some trinuclear ferrocenyl based organos...
Assembly of dendrimers with redox-active [{CpFe(μ3-CO)} 4] clusters at the periphery and their application to oxo-anion and adenosine-5′-triphosphate sensing
Aranzaes, Jaime Ruiz,Belin, Colette,Astruc, Didier
, p. 132 - 136 (2006)
9, 16, or 27 [CpFe(μ3-CO)]4 clusters con...
Synthesis and liquid crystal properties of copper(II) and palladium(II) chelates with new ferrocene-containing enaminoketones
Kadkin, Oleg N.,Kim, Eun Ho,Kim, So Yeon,Choi, Moon-Gun
, p. 1301 - 1307 (2009)
Heterometallic liquid crystals are of sp...
Synthesis of new binuclear ferrocenyl compounds by hydrosilylation reactions
Teimuri-Mofrad, Reza,Mirzaei, Farzaneh,Abbasi, Hassan,D. Safa, Kazem
, p. 197 - 205 (2017)
Ferrocenyl silanes are prepared by treat...
A step towards development of promising trypanocidal agents: Synthesis, characterization and in vitro biological evaluation of ferrocenyl Mannich base-type derivatives
Paucar, Rocío,Martín-Escolano, Rubén,Moreno-Viguri, Elsa,Cirauqui, Nuria,Rodrigues, Carlos Rangel,Marín, Clotilde,Sánchez-Moreno, Manuel,Pérez-Silanes, Silvia,Ravera, Mauro,Gabano, Elisabetta
, p. 569 - 582 (2019)
Chagas disease is a neglected chronical ...
Copper and nickel complexes of the tetradentate ligand derived from the condensation of ferrocenoylacetone with 1,2-diaminoethane
Shi, Yao-Cheng,Shen, Wen-Bin,Yang, Hua-Mei,Song, Hai-Bin,Hu, Xiao-Ya
, p. 749 - 754 (2004)
Ferrocenoylacetone [C5H5FeC5H 4C(O)CH2C(...
The d4/d3 redox pairs [MX(CO)(η-RCCR)Tp′] z (z = 0 and 1): Structural consequences of electron transfer and implications for the inverse halide order
Adams, Christopher J.,Bartlett, Ian M.,Carlton, Susannah,Connelly, Neil G.,Harding, David J.,Hayward, Owen D.,Orpen, A. Guy,Patron, Elena,Ray, Christopher D.,Rieger, Philip H.
, p. 62 - 72 (2007)
The d4 halide complexes [MX(CO)(η-RCCR)T...
Synthesis of 5-(dimethylsilyl)pentylalkylferrocene-grafted HTPB (alkylFc-HTPB) via platinum-catalyzed hydrosilylation
Teimuri-mofrad, Reza,Safa, Kazem D.,Abedinpour, Saiedeh,Rahimpour, Keshvar
, p. 2177 - 2185 (2017)
In this work, at first alkylferrocene de...
1-Ethyl-3-methylimidazolium halogenoaluminate melts as reaction media for the Friedel-Crafts acylation of ferrocene
Surette, Jacqueline K. D.,Green, Laine,Singer, Robert D.
, p. 2753 - 2754 (1996)
Ionic liquid mediated Friedel-Crafts acy...
Synthesis and thermal performance of poly(cyclotriphosphazene- acetylferrocene) derivative
Zhao, Zhengping,Yu, Fengying
, p. 3639 - 3642 (2014)
Amino nucleophilic reagents were prepare...
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Carty,P.,Dove,M.F.A.
, p. 195 - 201 (1970)
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Ferrocenylalkylation of 2-mercaptobenzoxazoles
Osipova, E. Yu.,Ivanova,Rodionov,Korlyukov,Arkhipov,Simenel
, (2016)
Regioselectivity of the HBF4-catalyzed f...
Friedel-crafts acetylation of bis(trimethylsilyl)- and bis(tributylstannyl)ferrocene: implications on the mechanisms of acylation and proton exchange of ferrocene derivatives
Cunningham Jr., Allan F.
, p. 4864 - 4870 (1991)
The first unequivocal examples of interm...
A simple synthetic approach for the transformation of (S)-Ugi's amine
Zha, Gao-Feng,Xu, Wei-Yun,Dai, Peng,Lai, Xiao-Yan,Liu, Wei,Shen, Yong-Cun
, p. 1301 - 1304 (2014)
A simple synthetic approach for the tran...
Bismuth subnitrate-catalyzed markovnikov-type alkyne hydrations under batch and continuous flow conditions
?tv?s, Sándor B.,Fül?p, Ferenc,Szécsényi, Zsanett
, (2021/05/31)
Bismuth subnitrate is reported herein as...
METAL-ORGANIC POLYHEDRAL INCLUDING METALLOCENE STRUCTURE AND METHOD FOR PREPARING THE SAME
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Paragraph 0136, (2021/06/22)
Disclosed are a metal-organic polyhedron...
Novel meso-substituted ferrocene-appended porphyrins: Synthesis, characterization, and electrochemical evaluation
Payami, Elmira,Neshad, Saeed,Aghaiepour, Alireza,Teimuri-Mofrad, Reza
, (2021/09/08)
This paper focuses on the synthesis of t...
1271-55-2 Process route
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![(E)-1-[4-(methoxy-benzoyloxyimino)ethyl]ferrocene](/upload/2024/8/ee0dbc0d-9703-41d3-bc75-da3c8e61733c.png)
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(E)-1-[4-(methoxy-benzoyloxyimino)ethyl]ferrocene
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- 1271-55-2
acetylferrocene
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- 100-09-4
4-methoxybenzoic acid
| Conditions | Yield |
|---|---|
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With water; In methanol; for 1.16667h; Solvent; Inert atmosphere; Photolysis;
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90 %Spectr. |
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![(E)-1-[(p-styrenesulfonoyloxyimino)ethyl]ferrocene](/upload/2024/8/89002ef3-e4d7-4116-bd31-05ea80d08d7d.png)
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(E)-1-[(p-styrenesulfonoyloxyimino)ethyl]ferrocene
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- 1271-55-2
acetylferrocene
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- 98-70-4,28210-41-5
styrene-4-sulfonic acid
| Conditions | Yield |
|---|---|
|
With water; In methanol; for 1.16667h; Inert atmosphere; Photolysis;
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82 %Spectr. |
1271-55-2 Upstream products
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102-54-5
ferrocene
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75-34-3
1,1-dichloroethane
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506-96-7
Acetyl bromide
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17333-74-3
2-methylbenzene diazonium
1271-55-2 Downstream products
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1277-49-2
1-ferrocenylethanol
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1271-42-7
ferrocenecarboxylic acid
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1271-51-8
vinyl ferrocene
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7647-01-0
hydrogenchloride
2254784343