4-Methoxyphenylacetone
4-Methoxyphenylacetone
Offer Chemical Raw Material 4-Methoxyphenylacetone 122-84-9 In Stock
- Molecular Formula:C10H12O2
- Molecular Weight:164.204
- Appearance/Colour:pale yellow liquid
- Vapor Pressure:0.00789mmHg at 25°C
- Melting Point:<-15 °C
- Refractive Index:n20/D 1.525(lit.)
- Boiling Point:268 °C at 760 mmHg
- Flash Point:101.7 °C
- PSA：26.30000
- Density:1.027 g/cm3
- LogP:1.82670
4-Methoxyphenylacetone(Cas 122-84-9) Usage
|
Preparation |
Obtained by boiling α- or β-anetholglycol with a 2% solution of sulfuric acid, or from 1-(p-methoxyphenyl)-propan-1,2-ol by treatment with diluted sulfuric acid. |
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 61, p. 1748, 1996 DOI: 10.1021/jo9518314 |
|
Flammability and Explosibility |
Notclassified |
|
Safety Profile |
Moderately toxic by ingestion andother routes. A skin irritant. A flammable liquid. |
|
Taste threshold values |
Taste characteristics at 15 ppm: sweet spicy, with green anisic, minty nuances. |
|
General Description |
Asymmetric amination of 4-methoxyphenylacetone was studied. |
InChI:InChI=1/C10H12O2/c1-8(11)7-9-3-5-10(12-2)6-4-9/h3-6H,7H2,1-2H3
122-84-9 Relevant articles
Preparation of a highly congested carbazoyl-derived p,n-type phosphine ligand for acetone monoarylations
Fu, Wai Chung,Zhou, Zhongyuan,Kwong, Fuk Yee
, p. 1553 - 1558 (2016)
We report a newly developed carbazoyl-de...
-
Fort,Roberts
, p. 584,589 (1956)
-
Aryl C-F bond functionalization preparation method
-
Paragraph 0052; 0089-0098, (2021/09/29)
The invention relates to the technical f...
Catalytic Aerobic Oxidation of Alkenes with Ferric Boroperoxo Porphyrin Complex; Reduction of Oxygen by Iron Porphyrin
Kimura, Kento,Kurahashi, Takuya,Matsubara, Seijiro,Murano, Shunpei
supporting information, p. 2493 - 2497 (2021/12/29)
We herein describe the development of a ...
Markovnikov Wacker-Tsuji Oxidation of Allyl(hetero)arenes and Application in a One-Pot Photo-Metal-Biocatalytic Approach to Enantioenriched Amines and Alcohols
Albarrán-Velo, Jesús,Gotor-Fernández, Vicente,Lavandera, Iván
, p. 4096 - 4108 (2021/08/19)
The Wacker-Tsuji aerobic oxidation of va...
Photoredox-Catalyzed Dehydrogenative Csp3-Csp2Cross-Coupling of Alkylarenes to Aldehydes in Flow
Griffiths, Oliver M.,Esteves, Henrique A.,Chen, Yiding,Sowa, Karin,May, Oliver S.,Morse, Peter,Blakemore, David C.,Ley, Steven V.
, p. 13559 - 13571 (2021/10/01)
Executing photoredox reactions in flow o...
122-84-9 Process route
-
-
4180-23-8,25086-72-0,63589-56-0
E-1-(4'-methoxyphenyl)prop-1-ene
-
-
122-84-9
4-methoxybenzyl methyl ketone
-
-
123-11-5
4-methoxy-benzaldehyde
-
-
100-09-4
4-methoxybenzoic acid
| Conditions | Yield |
|---|---|
|
at 140 - 150 ℃;
|
-
-
131029-01-1,30314-64-8
1-(4-methoxyphenyl)propan-2-ol
-
-
122-84-9
4-methoxybenzyl methyl ketone
-
-
58993-79-6,23239-32-9
(R)-(-)-p-methoxyamphetamine
| Conditions | Yield |
|---|---|
|
With
amine dehydrogenase ChiAmDH; secondary alcohol dehydrogenase from Thermoanaerobacter ethanolicus W110A/G198D mutant; nicotinamide adenine dinucleotide; ammonium chloride;
pH=9;
enantioselective reaction;
Enzymatic reaction;
|
> 99 % ee |
122-84-9 Upstream products
-
51410-46-9
2-(4-methoxyphenyl)-3-methyloxirane
-
5435-44-9
(E)-3-Ureido-but-2-enoic acid ethyl ester
-
1712-69-2
1-isopropenyl-4-methoxybenzene
-
131029-01-1
1-(4-methoxyphenyl)propan-2-ol
122-84-9 Downstream products
-
5739-33-3
4-[3-(4-methoxy-phenyl)-thiopropionyl]-morpholine
-
27567-52-8
1-(4-methoxy-phenyl)-2-pyridin-2-yl-propan-2-ol
-
101287-18-7
1-(4-methoxy-phenyl)-2-methyl-3-[2]pyridyl-propan-2-ol
-
877-99-6
1-methoxy-4-(2-methyl-1-propenyl)benzene
